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Author(s):   Baklanov, A.V.; Krasnoperov, L.N.
Title:   Oxalyl Chloride-A Clean Source of Chlorine Atoms for Kinetic Studies
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   97 - 103
Year:   2001
Reference type:   Journal article
Squib:   2001BAK/KRA97-103

Reaction:   (COCl)2 + ·ClCO + ClCO + Cl2
Reaction order:   2
Temperature:   300 K
Pressure:  1.00 - 100 bar
Rate expression:   4.0x10-14 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:   He
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

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