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Author(s):   Husain, D.; Sealy, I.P.
Title:   The reaction of ground state lead atoms Pb(63P0), with CH3Cl, C2H5Cl, n-C3H7Cl and SF6 at elevated temperatures by time-resolved atomic resonance absorption spectroscopy
Journal:   J. Photochem.
Volume:   34
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986HUS/SEA245

Reaction:   n-C3H7Cl + Pb1-C3H7 + PbCl
Reaction order:   2
Temperature:   595 - 794 K
Pressure:  4.51E-2 - 0.20 bar
Rate expression:   7.21x10-11 [±1.83x10-11 cm3/molecule s] e-65767 [±3293 J/mole]/RT
Bath gas:   n-C3H7Cl
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
595 1.21E-16
600 1.36E-16
625 2.30E-16
650 3.74E-16
675 5.87E-16
700 8.92E-16
725 1.32E-15
750 1.89E-15
775 2.66E-15
794 3.40E-15