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Author(s):   Wu, F.; Carr, R.W.
Title:   Kinetics of CH2ClO Radical Reactions with O2 and NO, and the Unimolecular Elimination of HCl
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   1423 - 1432
Year:   2001
Reference type:   Journal article
Squib:   2001WU/CAR1423-1432

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2001WU/CAR1423-1432   O2 + CH2ClO → HC(O)Cl + HO2  265 - 306   2.00E-12       7766   8.71E-14  2
  2001WU/CAR1423-1432   NO2 + CH2ClO → Products  265 - 306   2.70E-12           2.70E-12  2
  2001WU/CAR1423-1432   CH2ClO → HCO + HCl  265 - 306   7.70E09       3.99E04   770  1

Search returned 3 records.