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Author(s):   Park, M.J.; Jang, S.C.; Choi, J.H.
Title:   A combined crossed-beam and theoretical study of the reaction dynamics of O(P-3)+C2H3 -> C2H2+OH: Analysis of the nascent OH products with the preferential population of the Pi(A ') component
Journal:   J. Chem. Phys.
Volume:   137
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012PAR/JAN204311

Reaction:   C2H3 + C2H2 + ·OH
Reaction order:   2
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Pressure dependence:   None reported
Experimental procedure:   Molecular beam
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Laser induced fluorescence
Comments:   The gas-phase reaction dynamics of ground-state atomic oxygen with vinyl radicals has been investigated using a combination of high-resolution laser-induced fluorescence spectroscopy in a crossed-beam configuration and ab initio calculations. No rate constant values were obtained.

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