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Title: Kinetics and mechanism of the thermal decomposition of 4-methylpent-1-ene
Journal: J. Chem. Soc.
Page(s):
Year: 1965
Reference type: Journal article
Squib: 1965TAN7436
Reaction:
(CH3)2CHCH2CH=CH2 → ·CH2CH=CH2 + 2-C3H7
Reaction order:
1
Temperature:
743 - 803
K
Pressure: 3.33E-2 - 0.27 bar
Rate expression:
5.0x109 [s-1] e-184581 [J/mole]/RT
Bath gas:
(CH3)2CHCH2CH=CH2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 743 | 5.28E-4 |
| 750 | 6.98E-4 |
| 775 | 1.81E-3 |
| 800 | 4.44E-3 |
| 803 | 4.92E-3 |