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Title: Rate Measurements for the Reactions H + NO2 → OH + NO and H + NOCl → HCl + NO by Lyman-α Fluorescence
Journal: Ber. Bunsenges. Phys. Chem.
Volume: 80
Page(s):
Year: 1976
Reference type: Journal article
Squib: 1976WAG/WEL1023
Reaction:
NO2 + H· → ·OH + NO
Reaction order:
2
Temperature:
240 - 460
K
Pressure: 3.47E-3 bar
Rate expression:
7.14x10-10 [±2.99x10-10 cm3/molecule s] e-4199 [±714 J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Resonance fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 240 | 8.71E-11 |
| 250 | 9.47E-11 |
| 275 | 1.14E-10 |
| 300 | 1.33E-10 |
| 325 | 1.51E-10 |
| 350 | 1.69E-10 |
| 375 | 1.86E-10 |
| 400 | 2.02E-10 |
| 425 | 2.18E-10 |
| 450 | 2.32E-10 |
| 460 | 2.38E-10 |