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Author(s):   Hidaka, Y.; Higashihara, T.; Ninomiya, N.; Oshita, H.; Kawano, H.
Title:   Thermal isomerization and decomposition of 2-butyne in shock waves
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   10977 - 10983
Year:   1993
Reference type:   Journal article
Squib:   1993HID/HIG10977-10983

Reaction:   2-butyne1,2-butadiene
Reaction order:   1
Temperature:   1100 - 1600 K
Rate expression:   3.0x1013 [s-1] e-280198 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 1.49E0
1150 5.63E0
1200 1.91E1
1250 5.87E1
1300 1.66E2
1350 4.32E2
1400 1.05E3
1450 2.42E3
1500 5.25E3
1550 1.08E4
1600 2.14E4