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Author(s):   Hoyermann, K.; Nothdurft, J.; Olzmann, M.; Wehmeyer, J.; Zeuch, T.
Title:   Formation and decomposition of chemically activated cyclopentoxy radicals from the c-C5H9+O reaction
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   3165 - 3173
Year:   2006
Reference type:   Journal article
Squib:   2006HOY/NOT3165-3173

Reaction:   cyclopentoxy (chemically activated) → Cyclopentanone +
Reaction order:   1
Reference reaction:   cyclopentoxy (chemically activated) → Products
Reference reaction order:   1
Temperature:   298 K
Pressure:  4.00E-3 bar
Rate expression:   3.1x10-1±2.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Branching ratio for beta fission of H from chemically activated c-C5H9O. Products were quantitatively identified from the FTIR reaction spectra and identified with the reaction channels.

Carbon centered radicals R were produced from the reaction of F atoms (microwave discharge of F2/He) with the precursor RH species: RH + F -> R + HF. O atoms were produced via the microwave discharge of O2/He mixtures and allowed to react with cyclopentyl radical to produce the chemically activated c-C5H9O

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