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Author(s):   Canosa-Mas, C.E.; Hutton-Squire, H.R.; King, M.D.; Stewart, D.J.; Thompson, K.C.; Wayne, R.P
Title:   Laboratory Kinetic Studies of the Reactions of Cl Atoms with Species of Biogenic Origin: δ3-Carene, Isoprene, Methacrolein and Methyl Vinyl Ketone
Journal:   J. Atmos. Chem.
Volume:   34
Page(s):   163 - 170
Year:   1999
Reference type:   Journal article
Squib:   1999CAN/HUT163-170

Reaction:   CH2=C(CH3)CH=CH2 + ·Cl → Products
Reaction order:   2
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   4.0x10-10±8.0x10-1
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography
Comments:   The rate constant agrees with previous studies: 1997RAG/FIN1509-1517, 1998BED/LAV953-959, and 1997NOT/LEB42-425.

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