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Author(s):   Suh, I.; Zhang, R.
Title:   Kinetic Studies of Isoprene Reactions Initiated by Chlorine Atom
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   6590 - 6596
Year:   2000
Reference type:   Journal article
Squib:   2000SUH/ZHA6590-6596

Reaction:   CH2=C(CH3)CH=CH2 + ·Cl → Products
Reaction order:   2
Reference reaction:   Br2 + ·ClBr· + BrCl
Temperature:   298 K
Pressure:  6.67E-3 - 1.33E-2 bar
Rate expression:   4.0x10-10 [±3.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Comments:   The Cl concentration was determined using the titration reaction Cl + Br2 -> BrCl + Br, k = 2.3 x 10-10 exp{-(135 ± 60)/T} cm3 molecule-1 s-1

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