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Title: The pyrolysis of chloroalkenes. Part III. The molecular mode of decomposition of the 1:2-dichloroethylenes
Journal: J. Chem. Soc.
Page(s):
Year: 1956
Reference type: Journal article
Squib: 1956GOO/HOW2640
Reaction:
(Z)-CHCl=CHCl → HCCCl + HCl
Reaction order:
1
Temperature:
633 - 748
K
Pressure: 4.13E-2 - 0.43 bar
Rate expression:
3.6x1012 [s-1] e-220334 [J/mole]/RT
Bath gas:
(Z)-CHCl=CHCl
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 633 | 2.37E-6 |
| 650 | 7.09E-6 |
| 675 | 3.21E-5 |
| 700 | 1.30E-4 |
| 725 | 4.81E-4 |
| 748 | 1.48E-3 |