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Author(s):   Goodall, A.M.; Howlett, K.E.
Title:   The pyrolysis of chloroalkenes. Part III. The molecular mode of decomposition of the 1:2-dichloroethylenes
Journal:   J. Chem. Soc.
Page(s):  
Year:   1956
Reference type:   Journal article
Squib:   1956GOO/HOW2640

Reaction:   (Z)-CHCl=CHClHCCCl + HCl
Reaction order:   1
Temperature:   633 - 748 K
Pressure:  4.13E-2 - 0.43 bar
Rate expression:   3.6x1012 [s-1] e-220334 [J/mole]/RT
Bath gas:   (Z)-CHCl=CHCl
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
633 2.37E-6
650 7.09E-6
675 3.21E-5
700 1.30E-4
725 4.81E-4
748 1.48E-3