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Author(s):   Yu, H.; Kennedy, E.M.; Uddin, A.; Sullivan, S.P.; Dlugogorski, B.Z.
Title:   Experimental and computational studies of the gas-phase reaction of halon 1211 with hydrogen
Journal:   Environ. Sci. Technol.
Volume:   39
Page(s):   3020 - 3028
Year:   2005
Reference type:   Journal article
Squib:   2005YU/KEN3020-3028

Reaction:   HCl + CBrF2CHBrF2 + ·Cl
Reaction order:   2
Temperature:   673 - 973 K
Pressure:  1.01 bar
Rate expression:   3.12x10-13 [cm3/molecule s] e-21600 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Experimental procedure:   Static or low flow - Data taken vs time
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
673 6.58E-15
675 6.65E-15
700 7.63E-15
725 8.67E-15
750 9.77E-15
775 1.09E-14
800 1.21E-14
825 1.34E-14
850 1.47E-14
875 1.60E-14
900 1.74E-14
925 1.88E-14
950 2.03E-14
973 2.16E-14