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Title: Gas-phase elimination kinetics of 1-substituted ethyl acetates effect of polar substituents at the α carbon of secondary acetates
Journal: Int. J. Chem. Kinet.
Volume: 15
Page(s):
Year: 1983
Reference type: Journal article
Squib: 1983HER/CHU205
Reaction:
CH3C(O)OCH(CH3)CH2F → CH3C(O)OH + CH2=CHCH2F
Reaction order:
1
Temperature:
583 - 683
K
Pressure: 5.20E-2 - 0.42 bar
Rate expression:
6.76x1012 [s-1] e-197884 [±1979 J/mole]/RT
Uncertainty:
1.40999997
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 583 | 1.26E-5 |
| 600 | 4.01E-5 |
| 625 | 1.96E-4 |
| 650 | 8.47E-4 |
| 675 | 3.29E-3 |
| 683 | 4.97E-3 |