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Author(s):   Parker, D.SN.; Zhang, F.T.; Kim, Y.S.; Kaiser, R.I.; Mebel, A.M.
Title:   On the Formation of Resonantly Stabilized C5H3 Radicals-A Crossed Beam and Ab Initio Study of the Reaction of Ground State Carbon Atoms with Vinylacetylene
Journal:   J. Phys. Chem. A
Volume:   115
Page(s):   593 - 601
Year:   2011
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2011PAR/ZHA593-601

Reaction:   Vinylacetylene + CC2H2 + CH=C=CH
Reaction order:   2
Reference reaction:   Vinylacetylene + C → Products
Reference reaction order:   2
Rate expression:   6.0x10-3
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is low pressure limit
Comments:   Electronic structure / statistical theory calculations were used to model branching for the conditions of molecular beam experiments. The quoted product branching fraction is for zero collision energy.

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