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DeSain, J.D.; Klippenstein, S.J.; Miller, J.A.; Taatjes, C.A.
Title: Measurements, Theory, and Modeling of OH Formation in Ethyl + O2 and Propyl + O2 Reactions
Journal: J. Phys. Chem. A
Page(s): 4415 - 4427
Reference type: Journal article
2-C3H7 + O2 → (CH3)2CHO2
Static cell (low flow), 296-700 K, He buffer typically 3.65E17 cm-3 (10-20 torr), O2 typically 6.3E15 cm-3. Radicals produced by RH + Cl -> R + HCl, where Cl produced by 193 nm excimer laser photolysis of CCl3F. OH detected using LIF at 281.996 nm.
Employed earlier quantum calculations (see references below) combined with master equation modeling to provide rate expressions for many reactions in this system. Only a few rate expressions are abstracted here.
Miller and Klippenstein, IJCK 33, 654 (2001)
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Rate constant values calculated from the Arrhenius expression: