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Title: Falloff curves for the unimolecular decomposition of two acyl radicals: RCO (+M) -> R+CO (+M) by pulsed laser photolysis coupled to time-resolved infrared diode laser absorption
Journal: Int. J. Chem. Kinet.
Volume: 37
Page(s): 611 - 624
Year: 2005
Reference type: Journal article
Squib: 2005DUS/ELM611-624
Reaction:
2-C3H7 + O2 → (CH3)2CHO2
Reaction order:
2
Temperature:
347 - 377
K
Pressure: 9.33E-3 - 0.13 bar
Rate expression:
3.2x10-12 [±1.0x10-12 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Vis-UV emission
Comments:
2-Methylpropionyl obtained from flash photolysis of 2-methylproponal/Cl2/N2.
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