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Title: Reaction of methyl radical with haloalkanes
Journal: Int. J. Chem. Kinet.
Volume: 16
Page(s): 579 - 590
Year: 1984
Reference type: Journal article
Squib: 1984SID/TRE579-590
Reaction:
CF2Cl2 + ·CH3 → CH3Cl + ·CClF2
Reaction order:
2
Reference reaction:
·CH3 + ·CH3 → C2H6
Temperature:
393 - 493
K
Rate expression:
2.09x10-12 [cm3/molecule s] e-47309 [±2835 J/mole]/RT
Uncertainty:
2.509999990463257
Bath gas:
(tert-C4H9O)2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 393 | 1.08E-18 |
| 400 | 1.39E-18 |
| 425 | 3.21E-18 |
| 450 | 6.75E-18 |
| 475 | 1.31E-17 |
| 493 | 2.03E-17 |