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Author(s):   Liang, P.; Mu, Y.J.; Daele, V.; Mellouki, A.
Title:   Rate Coefficients for Reactions of OH and Cl with Esters
Journal:   CHEMPHYSCHEM
Volume:   11
Page(s):   4097 - 4102
Year:   2010
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2010LIA/MU,4097-4102

Reaction:   n-Butyl propanoate + ·Cl → Products
Reaction order:   2
Reference reaction:   1-C6H14 + ·Cl → Products
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   1.58x10-10 [±1.3x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The errors quoted are twice the standard deviation arising from the average of the values obtained from different runs and do not include the uncertainty in the rate coefficients of the reference reactions, which could be as high as 15–20 %.

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