Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Liang, P.; Mu, Y.J.; Daele, V.; Mellouki, A.
Title:   Rate Coefficients for Reactions of OH and Cl with Esters
Volume:   11
Page(s):   4097 - 4102
Year:   2010
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2010LIA/MU,4097-4102

Reaction:   n-Butyl propanoate + ·Cl → Products
Reaction order:   2
Reference reaction:   1-C6H14 + ·Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   4.8x10-1±2.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The errors quoted correspond to twice the standard deviation arising from the least-squares fit of the data and do not include the estimated error in the reference rate constant.

View full bibliographic record.