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Title: Pyrolysis of diallyl oxalate vapour. Part 1 - Kinetics of the unsensitized decomposition
Journal: Trans. Faraday Soc.
Volume: 65
Page(s): 1350 - 1356
Year: 1969
Reference type: Journal article
Squib: 1969JAM/KAM1350-1356
Reaction:
(COOCH2CH=CH2)2 → Products
Reaction order:
1
Temperature:
403 - 463
K
Pressure: 1.07E-2 - 1.33E-2 bar
Rate expression:
1.0x1014 [s-1] e-167121 [±8314472 J/mole]/RT
Bath gas:
(COOCH2CH=CH2)2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 403 | 2.18E-8 |
| 425 | 2.89E-7 |
| 450 | 3.99E-6 |
| 463 | 1.40E-5 |