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Title: Thermolytic reactions of esters. Part V. Thermal stability of diallyl oxalate vapour; reactivity of allyl radicals
Journal: Recueil
Volume: 90
Page(s):
Year: 1971
Reference type: Journal article
Squib: 1971LOU469
Reaction:
(COOCH2CH=CH2)2 → Products
Reaction order:
1
Temperature:
653 - 784
K
Pressure: 1.01 bar
Rate expression:
6.31x1010 [s-1] e-179593 [J/mole]/RT
Bath gas:
Toluene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 653 | 2.72E-4 |
| 675 | 7.99E-4 |
| 700 | 2.51E-3 |
| 725 | 7.26E-3 |
| 750 | 1.96E-2 |
| 775 | 4.96E-2 |
| 784 | 6.84E-2 |