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Title: Kinetic Study of Cycloaddtion of Allyl Radical to Acetylene
Journal: Ind. Eng. Chem. Fundam.
Volume: 19
Page(s):
Year: 1980
Reference type: Journal article
Squib: 1980NOH/SAK340
Reaction:
(COOCH2CH=CH2)2 → Products
Reaction order:
1
Temperature:
703 - 783
K
Pressure: 1.01 bar
Rate expression:
2.0x1011 [s-1] e-187907 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 703 | 2.18E-3 |
| 725 | 5.79E-3 |
| 750 | 1.64E-2 |
| 775 | 4.33E-2 |
| 783 | 5.83E-2 |