Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Graham, R.A.; Winer, A.M.; Atkinson, R.; Pitts, J.N., Jr.
Title:   Rate Constants for the Reaction of HO2 with HO2, SO2 , CO, N2O, trans-2-Butene,and 2,3-Dimethyl-2-butene at 300 K
Journal:   J. Phys. Chem.
Volume:   83
Year:   1979
Reference type:   Journal article
Squib:   1979GRA/WIN1563

Reaction:   (E)-2-C4H8 + HO2 → Products
Reaction order:   2
Reference reaction:   HO2 + NO2HO2NO2
Temperature:   300 K
Pressure:  1.01 bar
Rate expression:   4.0x10-18 [cm3/molecule s]
Rate constant is an upper limit.
Uncertainty:   2.0
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.