Author(s):   Rosas, F.; Lezama, J.; Mora, J.R.; Maldonado, A.; Cordova, T.; Chuchani, G.
Title:   Kinetics and Mechanisms of the Thermal Decomposition of 2-Methyl-1,3-dioxolane, 2,2-Dimethyl-1,3-dioxolane, and Cyclopentanone Ethylene Ketal in the Gas Phase. Combined Experimental and DFT Study
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   9228 - 9237
Year:   2012
Reference type:   Journal article
Squib:   2012ROS/LEZ9228-9237

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
2012ROS/LEZ9228-9237	1,3-Dioxolane, 2-methyl- → CH₃CHO + CH₃CHO	733 - 753	4.07E13	2.42E05	1
2012ROS/LEZ9228-9237	1,3-Dioxolane, 2,2-dimethyl- → Acetone + CH₃CHO	743 - 763	1.45E14	2.54E05	1
2012ROS/LEZ9228-9237	Cyclopentanone ethylene ketal → CH₃CHO + Cyclopentanone	733 - 754	3.02E13	2.38E05	1
2012ROS/LEZ9228-9237	1,3-Dioxolane, 2-methyl- → CH₃CHO + CH₃CHO	753 - 753	6.03E12	2.65E05	1
2012ROS/LEZ9228-9237	1,3-Dioxolane, 2,2-dimethyl- → Acetone + CH₃CHO	753 - 753	2.14E13	2.39E05	1
2012ROS/LEZ9228-9237	Cyclopentanone ethylene ketal → CH₃CHO + Cyclopentanone	753 - 753	8.71E12	2.34E05	1

Search returned 6 records.