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Accessibility information
Author(s):   Destriau, M.; Troe, J.
Title:   Thermal dissociation and recombination of alkyl and haloalkyl peroxynitrates: An SACM modelling study
Journal:   Int. J. Chem. Kinet.
Volume:   22
Page(s):   915 - 934
Year:   1990
Reference type:   Journal article
Squib:   1990DES/TRO915-934

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1990DES/TRO915-934   CH3O2· + NO2CH3O2NO2  233 - 373   7.51E-12           7.51E-12  2
  1990DES/TRO915-934   CH3O2· + NO2CH3O2NO2  233 - 373   2.50E-30   -5.50       2.50E-30  3
  1990DES/TRO915-934   C2H5OO· + NO2C2H5OONO2  233 - 373   7.51E-12           7.51E-12  2
  1990DES/TRO915-934   C2H5OO· + NO2C2H5OONO2  233 - 373   7.89E-30   -6.20       7.89E-30  3
  1990DES/TRO915-934   NO2 + CF3O2CF3OONO2  233 - 373   7.51E-12           7.51E-12  2
  1990DES/TRO915-934   NO2 + CF3O2CF3OONO2  233 - 373   3.01E-29   -6.40       3.01E-29  3
  1990DES/TRO915-934   NO2 + CCl3O2CCl3OONO2  233 - 373   7.51E-12           7.51E-12  2
  1990DES/TRO915-934   NO2 + CCl3O2CCl3OONO2  233 - 373   1.20E-28   -7.70       1.20E-28  3
  1990DES/TRO915-934   NO2 + CCl2FO2CFCl2OONO2  233 - 373   7.51E-12           7.51E-12  2
  1990DES/TRO915-934   NO2 + CCl2FO2CFCl2OONO2  233 - 373   1.70E-28   -6.70       1.70E-28  3
  1990DES/TRO915-934   NO2 + CClF2OO → CClF2OONO2  233 - 373   7.51E-12           7.51E-12  2
  1990DES/TRO915-934   NO2 + CClF2OO → CClF2OONO2  233 - 373   1.40E-28   -6.40       1.40E-28  3

Search returned 12 records.