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Author(s):   Sarzynski, D.; Gola, A.A.; Drys, A.; Brudnik, K.; Jodkowski, J.T.
Title:   Kinetic study of the reaction of chlorine atoms with bromoethane and D-bromoethane in the gas phase
Journal:   Chem. Phys. Lett.
Volume:   509
Page(s):   114 - 118
Year:   2011
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2011SAR/GOL114-118

Reaction:   Ethane-d5-, bromo- + ·Cl → Other Products + DCl
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Temperature:   298 - 527 K
Pressure:  0.13 bar
Rate expression:   2.8x10-11 [±2.0x10-12 cm3/molecule s] e-6236 [±249 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The error limits include the 2σ error of the derived rate constants ratio and the 2σ error of the reference rate constant.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.26E-12
300 2.30E-12
325 2.79E-12
350 3.28E-12
375 3.79E-12
400 4.29E-12
425 4.79E-12
450 5.29E-12
475 5.77E-12
500 6.25E-12
525 6.71E-12
527 6.75E-12