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Accessibility information
Author(s):   Sarzynski, D.; Gola, A.A.; Drys, A.; Brudnik, K.; Jodkowski, J.T.
Title:   Kinetic study of the reaction of chlorine atoms with bromoethane and D-bromoethane in the gas phase
Journal:   Chem. Phys. Lett.
Volume:   509
Page(s):   114 - 118
Year:   2011
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2011SAR/GOL114-118

Reaction:   Ethane-d5-, bromo- + ·Cl → Other Products + DCl
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Temperature:   298 - 527 K
Pressure:  0.13 bar
Rate expression:   2.8x10-11 [±2.0x10-12 cm3/molecule s] e-6236 [±249 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The error limits include the 2σ error of the derived rate constants ratio and the 2σ error of the reference rate constant.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.26E-12
300 2.30E-12
325 2.79E-12
350 3.28E-12
375 3.79E-12
400 4.29E-12
425 4.79E-12
450 5.29E-12
475 5.77E-12
500 6.25E-12
525 6.71E-12
527 6.75E-12