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 Author(s):   Sanders, W.A.; Lin, M.C.
Title:   Kinetics and mechanism of reactions of NF2 with olefins. Reinterpretation of existing data and estimation of C-N bond energies of alkyldifluoroamines
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   83
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987SAN/LIN905

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1987SAN/LIN905   C2H4 + NF2 → F2NCH2CH2  330 - 430   2.34E-14       6.19E04      2
  1987SAN/LIN905   C2H4 + NF2 → F2NCH2CH2  330 - 430   1.12E-32       6.24E04      3
  1987SAN/LIN905   CH2=CHCl + NF2 → CH2CH(NF2)Cl  330 - 430   4.68E-15       5.44E04      2
  1987SAN/LIN905   CH2=CHCl + NF2 → CH2CH(NF2)Cl  330 - 430   6.04E-33       5.52E04      3
  1987SAN/LIN905   1-C4H8 + NF2 → C2H5CHCH2NF2  330 - 430   3.47E-14       5.85E04      2
  1987SAN/LIN905   1-C4H8 + NF2 → C2H5CHCH2NF2  330 - 440   3.17E-34       4.18E04      3
  1987SAN/LIN905   CH3CH=CH2 + NF2 → CH3CHCH2NF2  330 - 430   8.92E-14       6.11E04      2
  1987SAN/LIN905   CH3CH=CH2 + NF2 → CH3CHCH2NF2  330 - 430   2.95E-33       5.02E04      3
  1987SAN/LIN905   Isobutene + NF2 → (CH3)2CCH2NF2  330 - 430   9.55E-15       4.98E04      2
  1987SAN/LIN905   Isobutene + NF2 → (CH3)2CCH2NF2  330 - 430   3.03E-32       5.06E04      3
  1987SAN/LIN905   Cyclopentene + NF2 → Cyclopentyl, 2-(difluoroamino)-  330 - 430   1.07E-15       4.61E04      2
  1987SAN/LIN905   Cyclopentene + NF2 → Cyclopentyl, 2-(difluoroamino)-  330 - 430   2.14E-32       5.31E04      3
  1987SAN/LIN905   (CH3)2C=CHCH3 + NF2 → CH3CH(NF2)C(CH3)2  330 - 430   2.66E-15       4.35E04      2
  1987SAN/LIN905   (CH3)2C=CHCH3 + NF2 → CH3CH(NF2)C(CH3)2  330 - 430   2.57E-33       4.18E04      3
  1987SAN/LIN905   (CH3)2C=C(CH3)2 + NF2 → (CH3)2C(NF2)C(CH3)2  330 - 430   2.82E-16       3.31E04      2
  1987SAN/LIN905   (CH3)2C=C(CH3)2 + NF2 → (CH3)2C(NF2)C(CH3)2  330 - 430   2.76E-33       3.97E04      3
  1987SAN/LIN905   (Z)-2-C4H8 + NF2 → CH3CH(NF2)CHCH3  330 - 430   1.32E-14       5.23E04      2
  1987SAN/LIN905   (Z)-2-C4H8 + NF2 → CH3CH(NF2)CHCH3  330 - 430   7.78E-33       5.11E04      3
  1987SAN/LIN905   CH2=CHBr + NF2 → CH2CH(NF2)Br  330 - 430   1.99E-14       5.85E04      2
  1987SAN/LIN905   CH2=CHBr + NF2 → CH2CH(NF2)Br  330 - 430   5.02E-33       5.52E04      3
  1987SAN/LIN905   (E)-2-C4H8 + NF2 → CH3CH(NF2)CHCH3  330 - 430   8.32E-15       5.11E04      2
  1987SAN/LIN905   (E)-2-C4H8 + NF2 → CH3CH(NF2)CHCH3  330 - 430   3.31E-32       5.31E04      3
  1987SAN/LIN905   CH3CHCH2NF2 → CH3CH=CH2 + NF2  330 - 430   2.45E13       5.99E04      1
  1987SAN/LIN905   CH3CHCH2NF2 → CH3CH=CH2 + NF2  330 - 430   8.14E-07       4.94E04      2
  1987SAN/LIN905   F2NCH2CH2 → C2H4 + NF2  330 - 430   3.55E12       5.73E04      1
  1987SAN/LIN905   F2NCH2CH2 → C2H4 + NF2  330 - 430   1.20E-06       5.65E04      2
  1987SAN/LIN905   C2H5CHCH2NF2 → 1-C4H8 + NF2  330 - 430   4.79E11       4.86E04      1
  1987SAN/LIN905   C2H5CHCH2NF2 → 1-C4H8 + NF2  330 - 430   4.47E-09       3.18E04      2
  1987SAN/LIN905   CH3CH(NF2)CHCH3 → (Z)-2-C4H8 + NF2  330 - 430   7.41E13       5.94E04      1
  1987SAN/LIN905   CH3CH(NF2)CHCH3 → (Z)-2-C4H8 + NF2  330 - 430   4.37E-05       5.77E04      2
  1987SAN/LIN905   CH3CH(NF2)CHCH3 → (E)-2-C4H8 + NF2  330 - 430   3.72E13       5.82E04      1
  1987SAN/LIN905   CH3CH(NF2)CHCH3 → (E)-2-C4H8 + NF2  330 - 430   1.48E-04       6.03E04      2
  1987SAN/LIN905   (CH3)2CCH2NF2 → Isobutene + NF2  330 - 430   3.39E09       3.01E04      1
  1987SAN/LIN905   (CH3)2CCH2NF2 → Isobutene + NF2  330 - 430   1.07E-08       3.13E04      2
  1987SAN/LIN905   CH3CH(NF2)C(CH3)2 → (CH3)2C=CHCH3 + NF2  330 - 430   5.25E11       4.06E04      1
  1987SAN/LIN905   CH3CH(NF2)C(CH3)2 → (CH3)2C=CHCH3 + NF2  330 - 430   4.90E-07       3.89E04      2
  1987SAN/LIN905   (CH3)2C(NF2)C(CH3)2 → (CH3)2C=C(CH3)2 + NF2  330 - 430   8.91E10       3.05E04      1
  1987SAN/LIN905   (CH3)2C(NF2)C(CH3)2 → (CH3)2C=C(CH3)2 + NF2  330 - 430   8.72E-07       3.68E04      2
  1987SAN/LIN905   Cyclopentyl, 2-(difluoroamino)- → Cyclopentene + NF2  330 - 430   7.24E10       4.18E04      1
  1987SAN/LIN905   Cyclopentyl, 2-(difluoroamino)- → Cyclopentene + NF2  330 - 430   1.45E-06       4.86E04      2
  1987SAN/LIN905   CH2CH(NF2)Cl → CH2=CHCl + NF2  330 - 430   3.72E10       3.97E04      1
  1987SAN/LIN905   CH2CH(NF2)Cl → CH2=CHCl + NF2  330 - 430   4.78E-08       4.06E04      2
  1987SAN/LIN905   CH2CH(NF2)Br → CH2=CHBr + NF2  330 - 430   2.09E12       5.11E04      1
  1987SAN/LIN905   CH2CH(NF2)Br → CH2=CHBr + NF2  330 - 430   5.25E-07       4.81E04      2
Search returned 44 records.