Author(s):   Tonokura, K.; Norikane, Y.; Koshi, M.; Nakano, Y.; Nakamichi, S.; Goto, M.; Hashimoto, S.; Kawasaki, M.; Anderson, M.P.S.; Hurley, M.D.; Wallington, T.J.
Title:   Cavity Ring-down Study of the Visible Absorption Spectrum of the Phenyl Radical and Kinetics of Its Reactions with Cl, Br, Cl₂, and O₂
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   5908 - 5917
Year:   2002
Reference type:   Journal article
Squib:   2002TON/NOR5908-5917

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	k(298.00 K)	Order
2002TON/NOR5908-5917	Phenyl + ·Cl → Chlorobenzene	298	1.20E-10		1.20E-10	2
2002TON/NOR5908-5917	Phenyl + Br· → Bromobenzene	298	7.00E-11		7.00E-11	2
2002TON/NOR5908-5917	Phenyl + Cl₂ → Chlorobenzene + ·Cl	280 - 330	1.00E-12	-8314	2.87E-11	2
2002TON/NOR5908-5917	Phenyl + O₂ → Phenyl dioxy-	296	1.40E-11			2
Reference reaction: Phenyl + Cl₂ → Products					2

Search returned 4 records.