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Author(s):   Sidebottom, H.W.; Tedder, J.M.; Walton, J.C.
Title:   Free radical addition to olefins. Part 4.-The light-induced addition of sulphur chloride pentafluoride to ethylene
Journal:   Trans. Faraday Soc.
Volume:   65
Year:   1969
Reference type:   Journal article
Squib:   1969SID/TED2103

Reaction:   C2H4 + SF5 → SF5CH2CH2·
Reaction order:   2
Reference reaction:   SF5 + SF5S2F10
Temperature:   313 - 397 K
Pressure:  0.21 bar
Rate expression:   6.61x10-16 [cm3/molecule s] e-7949 [J/mole]/RT
Bath gas:   SF5Cl
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
313 3.12E-17
325 3.49E-17
350 4.30E-17
375 5.16E-17
397 5.95E-17