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Accessibility information
Author(s):   Lynch, P. T.; Annesley, C. J.; Tranter, R. S.
Title:   Dissociation of ortho-benzyne radicals in the high temperature fall-off regime
Journal:   Proc. Combust. Inst.
Volume:   35
Page(s):   145 - 152
Year:   2015
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2015LYN/ANN145-152

Reaction:   Fluorobenzene → o-C6H4 + HF
Reaction order:   1
Temperature:   2050 - 2980 K
Pressure:  4.00E-2 - 0.16 bar
Rate expression:   9.72x1014 [s-1] (T/298 K)-0.00 e-395388 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Laser schlieren

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
2050 8.11E4
2100 1.41E5
2150 2.39E5
2200 3.94E5
2250 6.37E5
2300 1.01E6
2350 1.57E6
2400 2.39E6
2450 3.58E6
2500 5.27E6
2550 7.65E6
2600 1.10E7
2650 1.55E7
2700 2.16E7
2750 2.97E7
2800 4.04E7
2850 5.45E7
2900 7.26E7
2950 9.59E7
2980 1.13E8