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Accessibility information
Author(s):   Lynch, P. T.; Annesley, C. J.; Tranter, R. S.
Title:   Dissociation of ortho-benzyne radicals in the high temperature fall-off regime
Journal:   Proc. Combust. Inst.
Volume:   35
Page(s):   145 - 152
Year:   2015
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2015LYN/ANN145-152

Reaction:   Fluorobenzene → o-C6H4 + HF
Reaction order:   1
Temperature:   2050 - 2980 K
Pressure:  4.00E-2 bar
Rate expression:   9.98x1032 [s-1] (T/298 K)-18.01 e-548522 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Laser schlieren

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
2050 8.69E3
2100 1.21E4
2150 1.65E4
2200 2.19E4
2250 2.84E4
2300 3.62E4
2350 4.52E4
2400 5.55E4
2450 6.71E4
2500 7.99E4
2550 9.38E4
2600 1.09E5
2650 1.25E5
2700 1.41E5
2750 1.58E5
2800 1.75E5
2850 1.93E5
2900 2.10E5
2950 2.27E5
2980 2.37E5