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Accessibility information
Author(s):   Lynch, P. T.; Annesley, C. J.; Tranter, R. S.
Title:   Dissociation of ortho-benzyne radicals in the high temperature fall-off regime
Journal:   Proc. Combust. Inst.
Volume:   35
Page(s):   145 - 152
Year:   2015
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2015LYN/ANN145-152

Reaction:   Fluorobenzene → o-C6H4 + HF
Reaction order:   1
Temperature:   2050 - 2980 K
Pressure:  8.00E-2 bar
Rate expression:   3.12x1035 [s-1] (T/298 K)-19.52 e-590362 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Laser schlieren

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
2050 1.27E4
2100 1.80E4
2150 2.50E4
2200 3.38E4
2250 4.47E4
2300 5.78E4
2350 7.33E4
2400 9.12E4
2450 1.12E5
2500 1.34E5
2550 1.59E5
2600 1.86E5
2650 2.15E5
2700 2.45E5
2750 2.76E5
2800 3.08E5
2850 3.40E5
2900 3.72E5
2950 4.04E5
2980 4.22E5