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Accessibility information
Author(s):   Cvetanovic, R.J.
Title:   Evaluated chemical kinetic data for the reactions of atomic oxygen O(3P) with unsaturated hydrocarbons
Journal:   J. Phys. Chem. Ref. Data
Volume:   16
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987CVE261

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1987CVE261   Benzene + → Products  298 - 600   2.52E-11       1.77E04   1.99E-14  2
  1987CVE261   C2H4 + → Products  200 - 500   1.06E-11       6652   7.25E-13  2
  1987CVE261   C2H2 + → Products  250 - 1300   2.66E-11       1.29E04   1.46E-13  2
  1987CVE261   C2H2 + CO + ·CH2  300 - 2500   3.49E-12   1.50   7067      2
  1987CVE261   C2H2 + + HCCO  1000 - 2500   7.14E-10       5.07E04      2
  1987CVE261   CH3CCH + → Products  290 - 1300   2.18E-11       8314   7.59E-13  2
  1987CVE261   CH2=CHCl + → Products  290 - 450   5.65E-12       5571   5.96E-13  2
  1987CVE261   CH2=CHF + → Products  290 - 450   8.97E-12       8564   2.83E-13  2
  1987CVE261   CH2=CCl2 + → Products  298   9.80E-13           9.80E-13  2
  1987CVE261   CH2=CF2 + → Products  290 - 450   6.97E-12       9312   1.63E-13  2
  1987CVE261   C2HCl3 + → Products  298   9.80E-14           9.80E-14  2
  1987CVE261   CF2=CCl2 + → Products  290 - 450   5.81E-12       5488   6.35E-13  2
  1987CVE261   C2F3Cl + → Products  290 - 450   3.82E-11       1.08E04   4.87E-13  2
  1987CVE261   alpha-pinene + → Products  290 - 450   3.16E-10       5903   2.91E-11  2
  1987CVE261   1,2-Dimethylbenzene + → Products  298 - 600   2.49E-11       1.15E04   2.43E-13  2
  1987CVE261   1,2,4-Trimethylbenzene + → Products  298 - 400   1.49E-11       6652   1.02E-12  2
  1987CVE261   t-Butylbenzene + → Products  298   6.64E-14           6.64E-14  2
  1987CVE261   Trifluoromethylbenzene + → Products  298   5.81E-15           5.81E-15  2
  1987CVE261   Ethylbenzene + → Products  298   9.96E-14           9.96E-14  2
  1987CVE261   1,4-Dimethylbenzene + → Products  298 - 600   2.61E-11       1.17E04   2.30E-13  2
  1987CVE261   1-C4H8 + → Products  290 - 450   1.34E-11       2910   4.15E-12  2
  1987CVE261   1,3-Butadiene + → Products  290 - 500   2.32E-11       333   2.03E-11  2
  1987CVE261   1-butyne + CH3CH=CH2 + CO  298 - 1300   3.32E-11       6943   2.02E-12  2
  1987CVE261   CH2=CHCH2Cl + → Products  298   1.01E-12           1.01E-12  2
  1987CVE261   1,3-Dimethylbenzene + → Products  298 - 600   2.49E-11       1.01E04   4.15E-13  2
  1987CVE261   1,3,5-Trimethylbenzene + → Products  298 - 600   9.96E-12       3326   2.60E-12  2
  1987CVE261   Toluene + → Products  298 - 932   2.71E-11       1.43E04   8.43E-14  2
  1987CVE261   Chlorobenzene + → Products  298   4.98E-13           4.98E-13  2
  1987CVE261   1-C5H10 + → Products  290 - 450   1.59E-11       -108   1.66E-11  2
  1987CVE261   Cyclohexene + → Products  290 - 500   2.16E-11       249   1.95E-11  2
  1987CVE261   Pyridine + → Products  300 - 500   4.82E-12       1.05E04      2
  1987CVE261   CH3CH=CH2 + → Products  290 - 450   1.01E-11       2328   3.96E-12  2
  1987CVE261   iso-C4H8 + → Products  290 - 450   1.59E-11       -108   1.66E-11  2
  1987CVE261   C2F4 + → Products  290 - 400   2.66E-12       2577   9.39E-13  2
  1987CVE261   CF3CF=CF2 → Products  297 - 398   1.30E-12       9728   2.55E-14  2
  1987CVE261   beta-pinene + → Products  290 - 450   2.49E-10       5488   2.72E-11  2
  1987CVE261   Cyclopentene + → Products  290 - 450   2.37E-11       333   2.08E-11  2
  1987CVE261   C2HF3 + → Products  290 - 450   1.01E-11       7899   4.18E-13  2
  1987CVE261   CH3C(CF3)=CH2 + → Products  200 - 450   9.61E-12       7832   4.07E-13  2
  1987CVE261   CH3CH2CF=CF2 + → Products  298   4.07E-12           4.07E-12  2
  1987CVE261   CH3CH=CF2 + → Products  298   1.83E-12           1.83E-12  2
  1987CVE261   1,3-Butadiyne + → Products  298 - 1300   7.47E-11       8231   2.70E-12  2
  1987CVE261   Fluorobenzene + → Products  298   1.33E-14           1.33E-14  2
  1987CVE261   CH2=C=CH2 + → Products  290 - 500   2.82E-11       7732   1.25E-12  2
  1987CVE261   H2C=C=O + → Products  230 - 449   2.99E-12       5654   3.05E-13  2
  1987CVE261   2-butyne + CH3CH=CH2 + CO  290 - 360   9.96E-11       7483   4.86E-12  2
  1987CVE261   (CH3)2C=CHCH3 + → Products  290 - 400   2.82E-11       -1663   5.52E-11  2
  1987CVE261   1,2,3-Trimethylbenzene + → Products  298 - 400   1.66E-11       6652   1.13E-12  2
  1987CVE261   (CH3)2CHCH=CH2 + → Products  290 - 500   9.96E-12       2212   4.08E-12  2
  1987CVE261   (CH3)2C=C(CH3)2 + → Products  290 - 550   2.49E-11       -2494   6.82E-11  2
  1987CVE261   (Z)-2-C4H8 + → Products  290 - 500   1.10E-11       -1164   1.76E-11  2
  1987CVE261   Cyclohexene, 1-methyl- + → Products  290 - 450   2.32E-11       -3326   8.90E-11  2
  1987CVE261   1-C6H12 + → Products  298   4.65E-12           4.65E-12  2
  1987CVE261   1,3-Cyclohexadiene + → Products  290 - 450   2.32E-11       -3326   8.90E-11  2
  1987CVE261   CH2=CHBr + → Products  230 - 449   9.30E-12       6943   5.64E-13  2
  1987CVE261   (CH3)2C=C=O + → Products  230 - 449   5.98E-12       -4739   4.05E-11  2
  1987CVE261   (E)-2-C4H8 + → Products  290 - 450   2.16E-11       -83.14   2.23E-11  2
  1987CVE261   2-(Z)-C5H10 + → Products  298   1.66E-11           1.66E-11  2
  1987CVE261   CH2FCH2CH=CH2 + → Products  298   2.32E-12           2.32E-12  2
  1987CVE261   C2D4 + → Products  200 - 500   1.06E-11       6652   7.25E-13  2
  1987CVE261   CF2=CFCF=CF2 + → Products  298   3.65E-13           3.65E-13  2
  1987CVE261   Vinylacetylene + → Products  298 - 1300   4.98E-11       7566   2.35E-12  2
  1987CVE261   CH2=CHCH2F + → Products  298   8.30E-13           8.30E-13  2
  1987CVE261   C2D2 + → Products  298   1.43E-13           1.43E-13  2
  1987CVE261   Benzene-d6 + → Products  376 - 944   2.52E-11       1.77E04      2
  1987CVE261   C6H5CD3 + → Products  298 - 944   3.65E-11       1.50E04   8.70E-14  2
  1987CVE261   CH3CF=CH2 + → Products  298   1.99E-12           1.99E-12  2
  1987CVE261   CD3CD=CD2 + → Products  298   3.99E-12           3.99E-12  2
  1987CVE261   (Z)-CHF=CHF + → Products  290 - 450   1.19E-11       9728   2.35E-13  2
  1987CVE261   (E)-CHF=CHF + → Products  290 - 450   1.34E-11       8647   4.10E-13  2
  1987CVE261   d-Limonene + → Products  290 - 450   4.48E-10       3326   1.17E-10  2
  1987CVE261   CH3CH=C=O + → Products  230 - 449   4.82E-12       -2079   1.11E-11  2
  1987CVE261   + C2H5CH=C=O → Products  230 - 449   5.31E-12       -1829   1.11E-11  2
  1987CVE261   + CH2=CHCF3 → Products  298   4.15E-14           4.15E-14  2
  1987CVE261   + 1,2-Di(methyl-d3)benzene-d4 → Products  298 - 600   3.49E-11       1.29E04   1.92E-13  2

Search returned 75 records.