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Title: A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 ± 2 K
Journal: Int. J. Chem. Kinet.
Volume: 25
Page(s): 651 - 665
Year: 1993
Reference type: Journal article
Squib: 1993WAL/HUR651-665
Reaction:
CHF2CHF2 + ·F → HF + CHF2CF2
Reaction order:
2
Reference reaction:
CH4 + ·F → ·CH3 + HF
Temperature:
295
K
Pressure: 0.93 bar
Rate expression:
1.0x10-12 [±2.99x10-13 cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Fourier transform (FTIR)
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