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Author(s):   Fettis, G.C.; Trotman-Dickenson, A.F.
Title:   The reactions of bromine atoms and the strengths of C-H bonds
Journal:   J. Am. Chem. Soc.
Volume:   81
Page(s):
Year:   1959
Reference type:   Journal article
Squib:   1959FET/TRO5260

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	k(298.00 K)	Order
1959FET/TRO5260	CH₃Br + Br· → HBr + ·CH₂Br	331 - 472	0.73	1.11E04		2
Reference reaction: C₂H₆ + Br· → ·C₂H₅ + HBr					2
1959FET/TRO5260	C₂H₆ + Br· → ·C₂H₅ + HBr	285 - 418	1.52	1.36E04	6.40E-03	2
Reference reaction: C₃H₈ + Br· → 2-C₃H₇ + HBr					2
1959FET/TRO5260	C₃H₈ + Br· → 2-C₃H₇ + HBr	307 - 421	2.56	1.11E04		2
Reference reaction: iso-C₄H₁₀ + Br· → tert-C₄H₉ + HBr					2
1959FET/TRO5260	1-C₄H₁₀ + Br· → sec-C₄H₉ + HBr	261 - 371	8.26	1.14E04	0.08	2
Reference reaction: iso-C₄H₁₀ + Br· → tert-C₄H₉ + HBr					2

Search returned 4 records.