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Accessibility information
Author(s):   Fettis, G.C.; Trotman-Dickenson, A.F.
Title:   The reactions of bromine atoms and the strengths of C-H bonds
Journal:   J. Am. Chem. Soc.
Volume:   81
Year:   1959
Reference type:   Journal article
Squib:   1959FET/TRO5260

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1959FET/TRO5260   CH3Br + Br·HBr + ·CH2Br  331 - 472   0.73       1.11E04      2
  Reference reaction:  C2H6 + Br··C2H5 + HBr 2
  1959FET/TRO5260   C2H6 + Br··C2H5 + HBr  285 - 418   1.52       1.36E04   6.40E-03  2
  Reference reaction:  C3H8 + Br·2-C3H7 + HBr 2
  1959FET/TRO5260   C3H8 + Br·2-C3H7 + HBr  307 - 421   2.56       1.11E04      2
  Reference reaction:  iso-C4H10 + Br·tert-C4H9 + HBr 2
  1959FET/TRO5260   1-C4H10 + Br·sec-C4H9 + HBr  261 - 371   8.26       1.14E04   0.08  2
  Reference reaction:  iso-C4H10 + Br·tert-C4H9 + HBr 2

Search returned 4 records.