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Title: A kinetic study of the reaction of chlorine and fluorine atoms with CF3CHO at 295 ± 2 K
Journal: Int. J. Chem. Kinet.
Volume: 25
Page(s): 819 - 824
Year: 1993
Reference type: Journal article
Squib: 1993WAL/HUR819-824
Reaction:
CF3CHO + ·F → CF3C(O)· + HF
Reaction order:
2
Reference reaction:
CH4 + ·F → ·CH3 + HF
Temperature:
295
K
Pressure: 0.93 bar
Rate expression:
2.71x10-11 [±1.08x10-12 cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
IR absorption
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