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Title: Temperature-dependent rate coefficients for the reactions of Cl atoms with methyl methacrylate, methyl acrylate and butyl methacrylate at atmospheric pressure
Journal: Atmos. Environ.
Volume: 43
Page(s): 5996 - 6002
Year: 2009
Reference type: Journal article
Squib: 2009BLA/BEJ5996-6002
Reaction:
Methyl methacrylate + ·Cl → Products
Reaction order:
2
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
2.82x10-10 [±9.3x10-11 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
Isobutene, 1,3-butadiene, and propene were used as reference compounds. The uncertainties are a combination of the 2σ statistical errors from the linear regression analysis, to which an estimated error of 20% has been added to cover errors in the rate coefficients of the reference compounds. Nitrogen bath gas was used in some of the experiments.
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