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Author(s):   Blanco, M.B.; Bejan, I.; Barnes, I.; Wiesen, P.; Teruel, M.A.
Title:   Temperature-dependent rate coefficients for the reactions of Cl atoms with methyl methacrylate, methyl acrylate and butyl methacrylate at atmospheric pressure
Journal:   Atmos. Environ.
Volume:   43
Page(s):   5996 - 6002
Year:   2009
Reference type:   Journal article
Squib:   2009BLA/BEJ5996-6002

Reaction:   Methyl methacrylate + ·Cl → Products
Reaction order:   2
Reference reaction:   CH3CH=CH2 + ·Cl → Products
Temperature:   287 - 313 K
Pressure:  1.01 bar
Rate expression:   1.39x10-14 [±7.8x10-15 cm3/molecule s] e24145 [±3492 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
287 3.45E-10
300 2.22E-10
313 1.49E-10