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Applied Chemicals and Materials Division

Author(s):   Gibilisco, R. G.; Bejan, I.; Barnes, I.; Wiesen, P.; Teruel, M. A.
Title:   Rate coefficients at 298 K and 1 atm for the tropospheric degradation of a series of C-6, C-7 and C-8 biogenic unsaturated alcohols initiated by Cl atoms
Journal:   Atmos. Environ.
Volume:   94
Page(s):   564 - 572
Year:   2014
Reference type:   Journal article
Squib:   2014GIB/BEJ564-572

Reaction:   Methyl methacrylate + ·Cl → Products
Reaction order:   2
Temperature:   298 K
Rate expression:   2.82x10-10 [cm3/molecule s]
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Pressure dependence:   None reported
Comments:   Estimated based on correlation with the energy of the highest occupied molecular orbital (HOMO).

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