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Author(s):   Zhang, F.T.; Kaiser, R.I.; Golan, A.; Ahmed, M.; Hansen, N.
Title:   A VUV Photoionization Study of the Combustion-Relevant Reaction of the Phenyl Radical (C6H5) with Propylene (C3H6) in a High Temperature Chemical Reactor
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   3541 - 3546
Year:   2012
Reference type:   Journal article
Squib:   2012ZHA/KAI3541-3546

Reaction:   CH3CH=CH2 + Phenyl(Z)-1-Phenylpropene +
Reaction order:   2
Reference reaction:   CH3CH=CH2 + Phenyl → C9H10 (unspecified isomer) +
Reference reaction order:   2
Temperature:   1200 - 1500 K
Pressure:  0.40 bar
Rate expression:   3.0x10-2±3.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Other
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The reaction was studied using a high temperature tubular SiC reactor. The reaction products were probed in a supersonic beam by utilizing tunable vacuum ultraviolet (VUV) radiation from the Advanced Light Source and recording the photoionization efficiency (PIE) curves at individual mass-to-charge ratios.

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