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Author(s):   Husain, D.; Marshall, P.
Title:   Determination of absolute rate data for the reaction of atomic sodium, Na(32S1/2), with CF3Cl, CF2Cl2, CFCl3, CF3Br and SF6 as a function of temperature by time-resolved atomic resonance-absorption spectroscopy at λ = 589nm [Na(32PJ) → Na(32S1/2)]
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   81
Year:   1985
Reference type:   Journal article
Squib:   1985HUS/MAR613

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1985HUS/MAR613   CF3Br + Na → Products  644 - 918   4.00E-10       9977      2
  1985HUS/MAR613   CFCl3 + Na → Products  644 - 918   3.50E-10       6103      2
  1985HUS/MAR613   CF2Cl2 + Na → Products  644 - 918   5.60E-10       1.87E04      2
  1985HUS/MAR613   CF3Cl + Na·CF3 + NaCl  644 - 918   5.00E-10       3.70E04      2
  1985HUS/MAR613   SF6 + Na → Products  644 - 918   5.50E-10       1.03E04      2

Search returned 5 records.