Author(s):   Husain, D.; Marshall, P.
Title:   Determination of absolute rate data for the reaction of atomic sodium, Na(3²S₁_/₂), with CF₃Cl, CF₂Cl₂, CFCl₃, CF₃Br and SF₆ as a function of temperature by time-resolved atomic resonance-absorption spectroscopy at Î» = 589nm [Na(3²P_J) → Na(3²S₁_/₂)]
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   81
Page(s):
Year:   1985
Reference type:   Journal article
Squib:   1985HUS/MAR613

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
1985HUS/MAR613	CF₃Br + Na → Products	644 - 918	4.00E-10	9977	2
1985HUS/MAR613	CFCl₃ + Na → Products	644 - 918	3.50E-10	6103	2
1985HUS/MAR613	CF₂Cl₂ + Na → Products	644 - 918	5.60E-10	1.87E04	2
1985HUS/MAR613	CF₃Cl + Na → ·CF₃ + NaCl	644 - 918	5.00E-10	3.70E04	2
1985HUS/MAR613	SF₆ + Na → Products	644 - 918	5.50E-10	1.03E04	2

Search returned 5 records.