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Title: Shock tube measurements of the rate constants for seven large alkanes plus OH
Journal: Proc. Combust. Inst.
Volume: 35
Page(s): 189 - 196
Year: 2015
Reference type: Journal article
Squib: 2015BAD/ELW189-196
Reaction:
(CH3)3CCH2CH3 + ·OH → Other Products + H2O
Reaction order:
2
Temperature:
887 - 1327
K
Pressure: 1.52 bar
Rate expression:
2.0x10-10 [cm3/molecule s] e-18167 [J/mole]/RT
Uncertainty:
1.24000001
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Pressure dependence:
None reported
Experimental procedure:
Shock tube
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
Comments:
The uncertainty of the fitted Arrhenius Expression is estimated at ±24% at 1021 K.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 887 | 1.70E-11 |
| 900 | 1.76E-11 |
| 925 | 1.88E-11 |
| 950 | 2.01E-11 |
| 975 | 2.13E-11 |
| 1000 | 2.25E-11 |
| 1025 | 2.37E-11 |
| 1050 | 2.50E-11 |
| 1075 | 2.62E-11 |
| 1100 | 2.74E-11 |
| 1125 | 2.87E-11 |
| 1150 | 2.99E-11 |
| 1175 | 3.11E-11 |
| 1200 | 3.24E-11 |
| 1225 | 3.36E-11 |
| 1250 | 3.48E-11 |
| 1275 | 3.60E-11 |
| 1300 | 3.72E-11 |
| 1325 | 3.84E-11 |
| 1327 | 3.85E-11 |