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Author(s):   Badra, J.; Elwardany, A.; Farooq, A.
Title:   Shock tube measurements of the rate constants for seven large alkanes plus OH
Journal:   Proc. Combust. Inst.
Volume:   35
Page(s):   189 - 196
Year:   2015
Reference type:   Journal article
Squib:   2015BAD/ELW189-196

Reaction:   (CH3)3CCH2CH3 + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   887 - 1327 K
Pressure:  1.52 bar
Rate expression:   2.0x10-10 [cm3/molecule s] e-18167 [J/mole]/RT
Uncertainty:   1.24000001
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   The uncertainty of the fitted Arrhenius Expression is estimated at ±24% at 1021 K.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
887 1.70E-11
900 1.76E-11
925 1.88E-11
950 2.01E-11
975 2.13E-11
1000 2.25E-11
1025 2.37E-11
1050 2.50E-11
1075 2.62E-11
1100 2.74E-11
1125 2.87E-11
1150 2.99E-11
1175 3.11E-11
1200 3.24E-11
1225 3.36E-11
1250 3.48E-11
1275 3.60E-11
1300 3.72E-11
1325 3.84E-11
1327 3.85E-11