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Title: Rate coefficients for the thermal decomposition of BrONO2 and the heat of formation of BrONO2
Journal: J. Phys. Chem.
Volume: 100
Page(s): 19398 - 19405
Year: 1996
Reference type: Journal article
Squib: 1996ORL/TYN19398-19405
Reaction:
Br· + BrONO2 → Br2 + NO3
Reaction order:
2
Reference reaction:
CH3CHO + Br· → CH3CO + HBr
Temperature:
298
K
Pressure: 0.87 bar
Rate expression:
4.9x10-11 [±1.51x10-11 cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Fourier transform (FTIR)
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