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Author(s):   Gonzalez, A.C.; Schumacher, H.J.
Title:   Die kinetik und der mechanismus der thermischen reaktion zwischen schwefeltetrafluorid und fluor
Journal:   Z. Naturforsch. B
Volume:   36
Year:   1981
Reference type:   Journal article
Squib:   1981GON/SCH1381

Reaction:   F2 + SF4SF5 + ·F
Reaction order:   2
Temperature:   271 - 297 K
Pressure:  0.13 - 0.80 bar
Rate expression:   1.59x10-13 [±6.31x10-15 cm3/molecule s] e-49804 [±2486 J/mole]/RT
Bath gas:   F2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
271 3.99E-23
275 5.50E-23
297 2.76E-22