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Title: Die kinetik der thermischen reaktion zwischen schwefeltetrafluorid und fluor in Gegenwart von Sauerstoff
Journal: Z. Phys. Chem. (Munich)
Volume: 127
Page(s):
Year: 1981
Reference type: Journal article
Squib: 1981GON/SCH167
Reaction:
F2 + SF4 → SF5 + ·F
Reaction order:
2
Temperature:
259 - 280
K
Pressure: 0.29 - 0.96 bar
Rate expression:
1.51x10-13 [±2.99x10-15 cm3/molecule s] e-49804 [±2985 J/mole]/RT
Bath gas:
F2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 259 | 1.37E-23 |
| 275 | 5.24E-23 |
| 280 | 7.74E-23 |