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Author(s):   Aramendia, P.F.; Schumacher, H.J.
Title:   The kinetics and mechanism of the photochemical reaction between SF4 and fluorine at 365 nm
Journal:   J. Photochem.
Volume:   28
Year:   1985
Reference type:   Journal article
Squib:   1985ARA/SCH491

Reaction:   F2 + SF4SF5 + ·F
Reaction order:   2
Temperature:   213 - 244 K
Pressure:  2.67E-2 - 0.67 bar
Rate expression:   2.62x10-11 [cm3/molecule s] e-61111 [±1829 J/mole]/RT
Uncertainty:   1.1699999570846558
Bath gas:   CF4
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
213 2.71E-26
225 1.71E-25
244 2.17E-24