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Author(s):   Thiault, G.;Mellouki, A.
Title:   Rate constants for the reaction of OH radicals with n-propyl, n-butyl, iso-butyl and tert-butyl vinyl ethers
Journal:   Atmos. Environ.
Volume:   40
Page(s):   5566 - 5573
Year:   2006
Reference type:   Journal article
Squib:   2006THI/MEL5566-5573

Reaction:   n-C3H7OCH=CH2 + ·OH → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   1.0x10-10 [±2.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   The rate constant was measured relative to isoprene (k=1.01x10-10 cm3molecule-1s-1) and 2,3-dimethylbuta-1,3-diene (k=1.25x10-10 cm3molecule-1s-1)

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