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Author(s):   Peirone, S.A.; Abrate, J.PA.; Taccone, R.A.; Cometto, P.M.; Lane, S.I.
Title:   Kinetic study of the OH-initiated photo-oxidation of four unsaturated (allyl and vinyl) ethers under simulated atmospheric conditions
Journal:   Atmos. Environ.
Volume:   45
Page(s):   5325 - 5331
Year:   2011
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2011PEI/ABR5325-5331

Reaction:   n-C3H7OCH=CH2 + ·OH → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.00 bar
Rate expression:   1.1x10-10 [±4.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Isoprene and 1-methyl-1-cyclohexene were used as reference compounds. The errors quoted are twice the statistical deviation arising from the average of the values obtained in the independent experiments and do not include uncertainties from reference rate constants. An additional 15% could be considered to take into account the systematic error.

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