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Author(s):   Solly, R.K.; Golden, D.M.; Benson, S.W.
Title:   Kinetics and thermochemistry of the gas phase reaction of methyl ethyl ketone with iodine. II. the heat of formation and unimolecular decomposition of 2-iodo-3-butanone
Journal:   Int. J. Chem. Kinet.
Volume:   2
Page(s):   393 - 407
Year:   1970
Reference type:   Journal article
Squib:   1970SOL/GOL393-407

Reaction:   CH3C(O)CHICH3CH2=CHCOCH3 + HI
Reaction order:   1
Temperature:   554 - 628 K
Pressure:  9.87E-3 - 0.40 bar
Rate expression:   2.51x1013 [s-1] e-175435 [±1754 J/mole]/RT
Bath gas:   C2H5COCH3
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
554 7.23E-4
575 2.90E-3
600 1.34E-2
625 5.47E-2
628 6.43E-2