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Author(s):   Tarr, A.M.; Strausz, O.P.; Gunning, H.E.
Title:   Reactions of the ethynyl radical. Part 2.-With alkenes
Journal:   Trans. Faraday Soc.
Volume:   62
Page(s):  
Year:   1966
Reference type:   Journal article
Squib:   1966TAR/STR1221

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1966TAR/STR1221   C2H4 + ·C2HC2H2 + C2H3  298   0.55           0.55  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   C2H4 + ·C2HVinylacetylene +   298   0.78           0.78  2
  Reference reaction:  HC≡CBr + ·C2H1,3-Butadiyne + Br· 2
  1966TAR/STR1221   1-C4H8 + ·C2H → Other Products + C2H2  298   0.49           0.49  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   1,3-Butadiene + ·C2HC2H2 + CH2=CHCH=CH·  298   0.18           0.18  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   1-C5H10 + ·C2H → Other Products + C2H2  298   0.83           0.83  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   CH3CH=CH2 + ·C2H → Other Products + C2H2  298   0.31           0.31  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   Isobutene + ·C2H → Other Products + C2H2  298   0.44           0.44  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   Cyclopentene + ·C2H → Other Products + C2H2  298   1.27           1.27  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   (CH3)2C=CHCH3 + ·C2H → Other Products + C2H2  298   0.76           0.76  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   (CH3)2CHCH=CH2 + ·C2H → Other Products + C2H2  298   0.60           0.60  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   C2H5C(CH3)=CH2 + ·C2H → Other Products + C2H2  298   0.51           0.51  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   (CH3)2C=C(CH3)2 + ·C2HC2H2 + CH2C(CH3)=C(CH3)2  298   2.00           2.00  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   (Z)-2-C4H8 + ·C2H → Other Products + C2H2  298   0.51           0.51  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   1-C6H12 + ·C2H → Other Products + C2H2  298   1.29           1.29  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   (E)-2-C4H8 + ·C2H → Other Products + C2H2  298   0.52           0.52  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   2-(Z)-C5H10 + ·C2H → Other Products + C2H2  298   0.87           0.87  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   2-(E)-C5H10 + ·C2H → Other Products + C2H2  298   0.87           0.87  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   C2D4 + ·C2H → CH≡CCD=CD2 + D  298   0.58           0.58  2
  Reference reaction:  HC≡CBr + ·C2H1,3-Butadiyne + Br· 2
  1966TAR/STR1221   C2D4 + ·C2HHC≡CD + CD2CD  298   0.32           0.32  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   (CH3)3CCH2CH=CH2 + ·C2H → Other Products + C2H2  298   0.72           0.72  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   Methylenecyclobutane + ·C2H → Other Products + C2H2  298   0.84           0.84  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   CH3CF=CH2 + ·C2H → Other Products + C2H2  298   0.42           0.42  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   CD3CD=CD2 + ·C2H → Other Products + HC≡CD  298   0.40           0.40  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   ·C2H + (E)-2-C6H12 → Other Products + C2H2  298   0.88           0.88  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   ·C2H + CH2=CD2 → Other Products +   298   0.80           0.80  2
  Reference reaction:  HC≡CBr + ·C2H1,3-Butadiyne + Br· 2
  1966TAR/STR1221   ·C2H + CH2=CD2 → CH≡CCH=CD2 +   298   0.80           0.80  2
  Reference reaction:  HC≡CBr + ·C2H1,3-Butadiyne + Br· 2
  1966TAR/STR1221   ·C2H + CH2=CD2C2H2 + C2HD2  298   0.50           0.50  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2
  1966TAR/STR1221   ·C2H + (Z)-2-C6H12 → Other Products + C2H2  298   1.90           1.90  2
  Reference reaction:  HC≡CBr + ·C2H → BrC≡C· + C2H2 2

Search returned 28 records.